In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.COA of Formula: C41H35ClP2Ru
Synthesis and transition metal chemistry of ferrocenylbis(benzo-oxazaphosphininone)
The new ferrocenylbis(oxazaphosphininone), [Fe{C5H4P(OC6H4)(CO)N-(C2H4Cl)}2] (1) was synthesized by the reaction of bis(dichlorophosphino)ferrocene with two equivalents of 2(2?-hydroxy)phenyloxazoline in the presence of triethylamine in 83% yield. The reactions of 1 with aq. H2O2 or elemental sulfur afforded bis-chalcogenides [Fe{C5H4P(E)(OC6H4)(CO)N(C2H4Cl)}2] (2 E = O, 3 E = S). Treatment of 1 with [M(CO)4(C5H11N)2] (M = Mo, W), [RuCp(PPh3)2Cl] and [M(COD)Cl2] (M = Pd, Pt) afforded the chelate complexes [Fe{C5H4P(OC6H4)(CO)N(C2H4Cl)}2{M(CO)4}] (4 M = Mo, 5 M = W), [Fe{C5H4P(OC6H4)(CO)N(C2H4Cl)}2{RuCp(Cl)}] (7) and [Fe{C5H4P(OC6H4) (CO)N(C2H4Cl)}2{MCl2}] (8 M = Pd, 9 M = Pt), whereas the reaction of 1 with [Ru(eta6-p-cymene)Cl2]2, yielded a bimetallic complex [Fe{C5H4P(OC6H4)(CO)N(C2H4Cl)}2{RuCl2(eta6-p-cymene)}2] (6). The reaction between 1 and CuX in equimolar ratio also yielded binuclear complexes, [Fe{C5H4P(OC6H4)(CO)N(C2H4Cl)}2{CuX}2] (10 X = Cl, 11 X = Br, 12 X = I). All the compounds are characterized by spectroscopic methods and the structures of complexes 3, 7, 9 and 10 were confirmed by single crystal X-ray diffraction studies. The electrochemistry of 1, 3, 8, 9 and 12 is also reported.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI