Reference of 92361-49-4, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 92361-49-4, C46H45ClP2Ru. A document type is Article, introducing its new discovery.
Some neutral ruthenium vinylidene complexes and a novel 1,3-elimination reaction: Preparation of chiral ruthenium acetylides
Reactions of RuCl(PPh3)2Cp* with 1-alkynes in non-polar solvents afford the neutral vinylidene complexes RuCl(C=CHR)(PPh3)Cp* [R = Ph (X-ray structure), But, SiMe3, CO2Me]; a novel 1,3 elimination of HCl induced by NaOMe in the presence of a variety of ligands gives the chiral-at-metal complexes Ru(C?CR)(L)(PPh3)Cp* [L = CO, C2H4 (X-ray structure), PR3, P(OR)3, O2, S2, CS2 (for example)].
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI