Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, Recommanded Product: Dichloro(benzene)ruthenium(II) dimer.
Novel ruthenium-catalyzed cross-carbonylation of alkynes and 2-norbornenes to hydroquinones
Unsymmetrically substituted hydroquinones were obtained in high yields by the novel ruthenium-catalyzed cross-carbonylation of alkynes and 2-norbornenes. For example, treatment of 4-octyne and 2-norbornene with 2 mol % Ru3(CO)12 in N-methylpiperidine under 60 atm of carbon monoxide at 140C for 20 h gave the corresponding hydroquinone, 4,5-dipropyltricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-3,6-diol, in 85% yield. The reaction apparently involves a maleoylruthenium intermediate which is generated by the reaction of an alkyne and two molecules of carbon monoxide on the ruthenium.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI