In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.Computed Properties of C20H16Cl2N4Ru
Variable oxidation state sulfur-bridged bithiazole ligands tune the electronic properties of ruthenium(ii) and copper(i) complexes
The synthesis of homoleptic and heteroleptic ruthenium(ii) and copper(i) complexes containing sulfur-bridged bithiazole ligands of varying oxidation states are reported. The complexes have been characterized using 1D and 2D NMR spectroscopy, X-ray single crystal diffraction, electrochemistry, UV-vis absorbance and fluorescence spectroscopy. The stability, photophysical and electrochemical properties were found to be dependent on the oxidation state of the non-coordinating sulfur. The ruthenium and copper species were found to be non-emissive in solution at room temperature, though all displayed weak emission when doped in a PMMA matrix, which increased in intensity on cooling to 77 K. The electrochemical HOMO-LUMO gap was found to be dependent on the oxidation state of the sulfur in the bridging ligand in all complexes, illustrating an additional handle for tuning electrochemical properties.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI