The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Article£¬once mentioned of 10049-08-8, category: ruthenium-catalysts
Heterooctanuclear Cluster Complex Formation with Phosphine Participation: Synthesis, Structure, and Magnetic Properties of Co6Ru2(mp)10(PBu3n) 6 (H2mp = 2-Mercaptophenol, PBu3n = Tri-n-butylphosphine)
The reaction of CoCl2, RuCl3, Na2(mp), and PBu3n (H2mp = 2-mercaptophenol, PBu3n = tri-n-butylphosphine) in ethanol in the molar ratio of 0.75:0.25:1:1 gave the complex Co6Ru2(mp)10(PBu3n) 6. The heterooctanuclear complex consists of six cobalt and two ruthenium ions chelated to as well as bridged by the 2-mercaptophenol ligands in a near-dimeric fashion with two mu2-OR groups bridging the two Co3Ru(mp)5(PBu3n)3 fragments without a crystallographic center of symmetry. Each fragment is formed by binding two of the Co(mp)2(PBu3n) structural units and one Co(mp) species to a central Ru(III) ion through the S donors of the five mp ligands, while the sixth coordination site of the octahedral Ru environment is completed by a phosphine ligand in the axial position. The Co6Ru2 moiety exhibits a zigzag assembly constructed by the mu2-O and mu2-S bridges of the bidentate 2-mercaptophenol ligands in a highly asymmetric fashion. The Co atoms are square pyramidally coordinated with apices that are occupied by the phosphine ligands or an oxygen atom from a mp2- ligand. Variable-temperature magnetic susceptibilities that were measured in the temperature range 300-1.6 K reveal that the spin cluster exhibits weak antiferromagnetic exchange interactions, A quantitative interpretation of the magnetic data was carried out by the irreducible tensor operator approach. Crystal data of the complex are as follows: triclinic space group P1, a = 14.931(3) A, b = 23.195(5) A, c = 24.259(5) A, alpha = 74.91(3), beta= 74.83(3), gamma = 78.80(3), and Z = 2.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 10049-08-8 is helpful to your research., category: ruthenium-catalysts
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI