Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 15746-57-3, C20H16Cl2N4Ru. A document type is Article, introducing its new discovery., Recommanded Product: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)
New trimetallosupramolecular Ru(II) complexes containing ferrocenylpyrazole subunits
A series of bi-, tri-, and tetradentate acyclic redox-active ligands containing one or two ferrocenylpyrazole subunits and one or two pyridines, differently organized, have been prepared. Starting from Ru(bpy)2Cl2, mono- and bi-Ru(II) complexes have been obtained. Their study by NMR spectroscopy, electrochemistry, and molecular modeling shows important structural variations according to the relative position of the ferrocenyl substitutent and of the coordination site. The ferrocenylpyrazole seems to be a good moiety for electronic transfers and the interaction between metallic centers depends strongly on the ligand structure. CNRS-Gauthier-Villars.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI