Synthetic Route of 15746-57-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)
Synthesis and dynamic behavior of an anthyridine-ligated ruthenium complex
A ruthenium complex containing a 1,9,10-anthyridine derivative, [Ru(L)(bpy)2](PF6)2 ([1](PF6)2; L = 1,13,14-triazadibenz[a,j]anthracene, bpy = 2,2?-bipyridyl), was synthesized. X-ray crystal structural analysis of [1](PF6)2 showed that L is coordinated to the Ru center as a bidentate ligand. When [1 ](PF6)2 was dissolved in acetonitrile, a new complex incorporating one acetonitrile molecule, [Ru(L)( CH3CN)(bpy)2](PF6)2 ([2]( PF6)2), was formed. X-ray crystallographic data revealed that, in [2](PF6)2, L is coordinated to the Ru center in a monodentate fashion. The coordinated L in [2](PF6)2 shows a unique haptotropic rearrangement in an acetonitrile solution.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI