In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Safety of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Reactions of ‘GaI’ with organometallic transition metal halides
Two approaches towards the synthesis of phosphine ligated half-sandwich complexes [(etax-CxHx)M(PR3)2GaI2]n containing diiodogallyl ligands have been investigated. Insertion of ‘GaI’ into the Mo-I bond of (eta7-C7H7)Mo(CO)2I has been shown to yield the crystallographically characterized dimeric complex [(eta7-C7H7)Mo(CO)2GaI2]2 (2). Attempts to substitute the carbonyl ligands by the phosphine ligand dppe [dppe = bis(diphenylphosphino)ethane] have been shown instead to yield the sparingly soluble complex [(eta7-C7H7)Mo(CO)2GaI2]2(mu-dppe) (3) in which the phosphine bridges two [(eta7-C7H7)Mo(CO)2GaI2] units via a pair of P ? Ga donor/acceptor bonds. By contrast, attempts to insert ‘GaI’ directly into the metal-halogen bond of phosphine ligated complexes such as (eta5-C5H5)Ru(PPh3)2Cl or (eta5-C5H5)Ru(dppe)Cl have been shown to result in the formation of the tetraiodogallate species(eta5-C5H5)Ru(PPh3)2(mu-I)GaI3 (5) and [(eta5-C5H5)Ru(dppe)]+[GaI4]- (7).
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI