Archives for Chemistry Experiments of 15746-57-3

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Electric Literature of 15746-57-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)

Structure and spectroscopic studies of cis-bis(bipyridine) ruthenium(II) complexes of phenylcyanamide ligands

New ruthenium(II) complexes with cyanamide ligands, cis-[Ru(bpy) 2(Ipcyd)2] (1) and [Ru(bpy)2(OHpcyd) 2] (2) (bpy = 2,2?-bipyridine, Ipcyd = 4-iodophenylcyanamide anion, OHpcyd = 4-(3-hydroxy-3-methylbut-1-ynil)phenylcyanamide), have been prepared and characterized by UV-Vis, IR and 1H NMR spectroscopies as well as electrochemical technique (CV). The complex cis-[Ru(bpy) 2(Ipcyd)2] (1) crystallized with empirical formula of C34H24I2N8Ru in a monoclinic crystal system and space group of P21/c with a = 11.769(7) A, b = 24.188(12) A, c = 11.623(2) A, beta = 91.63(3), V = 3308(3) A3 and Z = 4.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI