Application of 138984-26-6. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about Cyclization of diazoacetamides catalyzed by N-heterocyclic carbene dirhodium(II) complexes. Author is Gomes, Luis F. R.; Trindade, Alexandre F.; Candeias, Nuno R.; Veiros, Luis F.; Gois, Pedro M. P.; Afonso, Carlos A. M..
The axial coordination of N-heterocyclic carbene ligands onto dirhodium(II) complexes was examined, together with its role in the intramol. C-H insertion reactions of α-diazoacetamides. The formation of a decarbonylated product occurs by a free-carbene mechanism in which the structures of the catalyst and the acetamide play a decisive role.
The article 《Cyclization of diazoacetamides catalyzed by N-heterocyclic carbene dirhodium(II) complexes》 also mentions many details about this compound(138984-26-6)Application of 138984-26-6, you can pay attention to it, because details determine success or failure
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI