Formula: C13H14BrNO2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 1-Boc-4-Bromoindole, is researched, Molecular C13H14BrNO2, CAS is 676448-17-2, about Chemoselective, scalable nickel-electrocatalytic O-arylation of alcohols.
The formation of aryl-alkyl ether bonds through cross coupling of alcs. with aryl halides represents a useful strategic departure from classical SN2 methods. Numerous tactics relying on Pd-, Cu-, and Ni-based catalytic systems have emerged over the past several years. Herein we disclose a Ni-catalyzed electrochem. driven protocol to achieve this useful transformation with a broad substrate scope in an operationally simple way. This electrochem. method does not require strong base, exogenous expensive transition metal catalysts (e.g.Ir, Ru), and can easily be scaled up in either a batch or flow setting. Interestingly, e-etherification exhibits an enhanced substrate scope over the mechanistically related photochem. variant as it tolerates tertiary amine functional groups in the alc. nucleophile.
The article 《Chemoselective, scalable nickel-electrocatalytic O-arylation of alcohols》 also mentions many details about this compound(676448-17-2)Formula: C13H14BrNO2, you can pay attention to it, because details determine success or failure
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI