Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 15418-29-8, is researched, Molecular C8H12BCuF4N4, about [Cu61(StBu)26S6Cl6H14]+: A Core-Shell Superatom Nanocluster with a Quasi-J36 Cu19 Core and an “”18-Crown-6″” Metal-Sulfide-like Stabilizing Belt, the main research direction is copper sulfide chloride hydride thiolate nanocluster complex preparation XPS; crystal structure copper sulfide chloride hydride thiolate nanocluster.Synthetic Route of C8H12BCuF4N4.
Although core-shell copper metal nanoclusters are important emerging materials for practical applications and fundamental scientific research, their synthesis lags behind that of gold and silver nanoclusters-challenged by copper’s much lower half-cell reduction potential, M(I)/M(0). To overcome this synthetic hurdle, we introduce a simple reaction strategy, involving the mild reducing agent borane tert-butylamine complex, to produce a core-shell superatom copper nanocluster, [Cu61(StBu)26S6Cl6H14]+ (-StBu; tert-Bu thiolate), which is the largest Cu(0)-containing structurally-solved core-shell copper cluster to-date. The nanocluster exhibits a quasi-elongated triangular gyrobicupola (quasi-J36,J36 = Johnson solid) Cu19 core and a shell held together by a novel “”18-crown-6″” metal-sulfide-like belt. Because of its stability, this cluster displays a single mol. ion peak in mass spectrometry measurements without any cluster fragmentation signals-a first observation of its kind for copper nanoclusters that paves the way for researchers to study nanocluster composition, charge, stability, and reaction mechanisms with at. precision that only mass spectrometry could afford.
The article 《[Cu61(StBu)26S6Cl6H14]+: A Core-Shell Superatom Nanocluster with a Quasi-J36 Cu19 Core and an “”18-Crown-6″” Metal-Sulfide-like Stabilizing Belt》 also mentions many details about this compound(15418-29-8)Synthetic Route of C8H12BCuF4N4, you can pay attention to it, because details determine success or failure
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
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