After consulting a lot of data, we found that this compound(15418-29-8)Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate can be used in many types of reactions. And in most cases, this compound has more advantages.
Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 15418-29-8, is researched, SMILESS is [Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-], Molecular C8H12BCuF4N4Journal, Polyhedron called Three cuprous coordination polymers based on bisbenzoxazole: Syntheses, structures, luminescence and electrochemical properties, Author is Qu, Yao; Wang, Cong; Wu, Yancong; Han, Xintong; Zhao, Kun; Huang, Guozhen; Shen, Kesheng; Li, Chuang; Wu, Huilu, the main research direction is copper benzoxazole coordination polymer preparation luminescence electrochem; crystal structure copper benzoxazole coordination polymer.Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate.
Three cuprous coordination polymers, namely: {[Cu(BBO)3]·PF6}n (1), {[Cu(BBO)2(CH3CN)2]·BF4}n (2) and {[Cu(BBO)2(SPPh3)]·BF4}n (3), bearing a bisbenzoxazole ligand, 2,2′-(1,4-butanediyl)bis-1,3-benzoxazole (BBO), have been synthesized, and structurally characterized by elemental analyses, IR, UV-Vis and single-crystal X-ray diffraction. The structural anal. revealed that the structures of coordination polymers 1 and 3 are both three-coordinated and show distorted trigonal planar geometry, but 2 is four-coordinated and a slightly distorted tetrahedron environment. In coordination polymer 1, adjacent copper(I) ions were bridged by three independent BBO to form a two-dimensional planar layer framework in which PF-6 anion is filled in the hole. Two BBO link Cu(I) ions into a one-dimensional zigzag chain in coordination polymer 2, while acetonitrile as an ancillary ligand distributed on both sides of the one-dimensional chain. Coordination polymer 3 exhibits a single-stranded helix chain structure by two BBO bridging adjacent copper(I) ions. Luminescence properties investigation show that 1 have two emission peaks, which attributed to π-π* and n-π* transitions. However 2 and 3 only had one emission peak, which may be attributed to [MLCT(d10(Cu)) → π*]. This may be due to the synergy of the auxiliary ligands in coordination polymers 2 and 3. The cyclic voltammogram of 1-3 represent quasi-reversible Cu2+/Cu+ pairs.
After consulting a lot of data, we found that this compound(15418-29-8)Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
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