The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Visible light-promoted carbodi(tri)fluoromethylthiolation of alkenes, the main research direction is fluoroalkylthiol dihydrobenzofuran preparation; alkene carbodifluoromethylthiolation carbotrifluoromethylthiolation visible light.HPLC of Formula: 60804-74-2.
Difunctionalization of alkenes represent a convenient way to complex mol. structure. Herein, visible light-induced intramol. carbodi(tri)fluoromethylthiolation of alkenes was reported. C-C and C-S were formed in the procedure. Various fluoroalkylthiol substituted 2,3-dihydrobenzofurans (DHB) was prepared Aryldiazonium salts derived from o-allyloxy anilines were used as precursors of aryl radicals. The following cyclization occurred, and the resulting alkyl radicals were trapped by shelf-stable reagent PhSO2SRf (Rf = SCF2H, SCF3). The direct difluoromethylthiolation on arenes was not observed A variety of atoms and functional groups were tolerated.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI