The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Quinolin-6-ylboronic acid( cas:376581-24-7 ) is researched.SDS of cas: 376581-24-7.Leister, Jeffrey; Chao, Darrian; Billingsley, Kelvin L. published the article 《Palladium-catalyzed prenylation of (hetero)aryl boronic acids》 about this compound( cas:376581-24-7 ) in Tetrahedron Letters. Keywords: arylboronic acid prenyl alc palladium catalyst regioselective prenylation; prenylarene preparation; phenylboronic acid allylic alc palladium catalyst allylation; allylbenzene preparation. Let’s learn more about this compound (cas:376581-24-7).
In this report, a palladium-catalyzed method for the cross-coupling of aryl and heteroaryl boronic acids with prenyl alcs. was described. Catalyst systems based on dialkylbiaryl phosphines were highly active for this transformation. These supporting ligands provided opportunities for tuning the efficiency and regioselectivity of carbon-carbon bond formation. In addition, this method was further extended to the cross-coupling of sym. allylic alcs. with aryl boronic acids.
After consulting a lot of data, we found that this compound(376581-24-7)SDS of cas: 376581-24-7 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI