Flexible application of in synthetic route 15418-29-8

The article 《Heteroleptic Cu(I) complexes with aromatic diimines and phosphines: Synthesis, structure, photophysical properties and THz time domain spectroscopy》 also mentions many details about this compound(15418-29-8)HPLC of Formula: 15418-29-8, you can pay attention to it, because details determine success or failure

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate( cas:15418-29-8 ) is researched.HPLC of Formula: 15418-29-8.Kuang, Xiao-Nan; Lin, Sen; Liu, Jian-Ming; Han, Hong-Liang; Liu, Min; Xin, Xiu-Lan; Yang, Yu-Ping; Li, Zhong-Feng; Jin, Qiong-Hua; Li, Si-Fan; Li, Yue-Xue; Feng, Yue-Bing published the article 《Heteroleptic Cu(I) complexes with aromatic diimines and phosphines: Synthesis, structure, photophysical properties and THz time domain spectroscopy》 about this compound( cas:15418-29-8 ) in Polyhedron. Keywords: heteroleptic copper aromatic diimine phosphine preparation crystal structure photophys; pyrazinophenanthroline dipyridophenazine diphosphino copper complex preparation crystal mol structure. Let’s learn more about this compound (cas:15418-29-8).

Nine novel copper(I) complexes with diphosphine and diimine ligands, namely [Cu(dpq)(xantphos)]BF4 (1), [Cu(dpq)(xantphos)]I (2), [Cu(dpq)(dppp)]BF4 (3), [Cu(dppz)(dppp)]BF4 (4), [Cu(dppz)(dppp)]I (5), [Cu(dppz)(pop)]I (6), [Cu(dpq)(pop)]I (7), [Cu(dpq)(pop)]Br (8), [Cu(dpq)(pop)]SCN (9) (dpq = pyrazino[2,3-f][1,10]phenanthroline, dppz = dipyrido[3,2-a:2′,3′-c]phenazine, xantphos = 9,9-dimethyl-4,5-bis(diphenylphosphanyl)xanthene, dppp = 1,3-bis(diphenylphosphino)propane, pop = 1,1′-[(Oxydi-2,1-phenylene)]bis[1,1-diphenylphosphine]), were characterized by single crystal x-ray diffraction, IR, elemental anal., 1H NMR, 31P NMR, fluorescence spectra and terahertz time domain spectroscopy (THz-TDS). These nine complexes were synthesized by the reactions of copper salts, diimine ligands and various of P-donor ligands through one-pot method. Single crystal x-ray diffraction reveals that complex 9 is of a simple mono-nuclear structure while complexes 6 and 7 are of dimer structures. For complex 8, hydrogen bonds and C-H···π interactions lead to the formation of a 1D infinite chain structure. Interestingly, complexes 1-5 show novel 2D or 3D network structures through C-H···π interactions. In addition, complexes 1-3 and 6-9 exhibit interesting fluorescence in the solid state at room temperature Among the nine complexes, complex 1 shows the highest quantum yield up to 37% and the lifetime of 1 is 6.0 μs. The terahertz (THz) time-domain spectra of these complexes were also studied.

The article 《Heteroleptic Cu(I) complexes with aromatic diimines and phosphines: Synthesis, structure, photophysical properties and THz time domain spectroscopy》 also mentions many details about this compound(15418-29-8)HPLC of Formula: 15418-29-8, you can pay attention to it, because details determine success or failure

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
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