The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Quinolin-6-ylboronic acid(SMILESS: OB(C1=CC=C2N=CC=CC2=C1)O,cas:376581-24-7) is researched.Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate. The article 《General Access to C-Centered Radicals: Combining a Bioinspired Photocatalyst with Boronic Acids in Aqueous Media》 in relation to this compound, is published in ACS Catalysis. Let’s take a look at the latest research on this compound (cas:376581-24-7).
Carbon-centered radicals are indispensable building blocks for modern synthetic chem. In recent years, visible light photoredox catalysis has become a promising avenue to access C-centered radicals from a broad array of latent functional groups, including boronic acids. Herein, we present an aqueous protocol wherein water features a starring role to help transform aliphatic, aromatic, and heteroaromatic boronic acids to C-centered radicals with a bioinspired flavin photocatalyst. These radicals are used to deliver a diverse pool of alkylated products, including three pharmaceutically relevant compounds, via open-shell conjugate addition to disparate Michael acceptors. The mechanism of the reaction is investigated by computational studies, deuterium labeling, radical-trapping experiments, and spectroscopic anal.
After consulting a lot of data, we found that this compound(376581-24-7)Reference of Quinolin-6-ylboronic acid can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI