Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 15418-29-8, is researched, SMILESS is [Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-], Molecular C8H12BCuF4N4Journal, Polyhedron called Three cuprous coordination polymers based on bisbenzoxazole: Syntheses, structures, luminescence and electrochemical properties, Author is Qu, Yao; Wang, Cong; Wu, Yancong; Han, Xintong; Zhao, Kun; Huang, Guozhen; Shen, Kesheng; Li, Chuang; Wu, Huilu, the main research direction is copper benzoxazole coordination polymer preparation luminescence electrochem; crystal structure copper benzoxazole coordination polymer.Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate.
Three cuprous coordination polymers, namely: {[Cu(BBO)3]·PF6}n (1), {[Cu(BBO)2(CH3CN)2]·BF4}n (2) and {[Cu(BBO)2(SPPh3)]·BF4}n (3), bearing a bisbenzoxazole ligand, 2,2′-(1,4-butanediyl)bis-1,3-benzoxazole (BBO), have been synthesized, and structurally characterized by elemental analyses, IR, UV-Vis and single-crystal X-ray diffraction. The structural anal. revealed that the structures of coordination polymers 1 and 3 are both three-coordinated and show distorted trigonal planar geometry, but 2 is four-coordinated and a slightly distorted tetrahedron environment. In coordination polymer 1, adjacent copper(I) ions were bridged by three independent BBO to form a two-dimensional planar layer framework in which PF-6 anion is filled in the hole. Two BBO link Cu(I) ions into a one-dimensional zigzag chain in coordination polymer 2, while acetonitrile as an ancillary ligand distributed on both sides of the one-dimensional chain. Coordination polymer 3 exhibits a single-stranded helix chain structure by two BBO bridging adjacent copper(I) ions. Luminescence properties investigation show that 1 have two emission peaks, which attributed to π-π* and n-π* transitions. However 2 and 3 only had one emission peak, which may be attributed to [MLCT(d10(Cu)) → π*]. This may be due to the synergy of the auxiliary ligands in coordination polymers 2 and 3. The cyclic voltammogram of 1-3 represent quasi-reversible Cu2+/Cu+ pairs.
After consulting a lot of data, we found that this compound(15418-29-8)Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate can be used in many types of reactions. And in most cases, this compound has more advantages.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI