Safety of Dirhodium(II) tetrakis(caprolactam). The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about The Oxidative Mannich Reaction Catalyzed by Dirhodium Caprolactamate. Author is Catino, Arthur J.; Nichols, Jason M.; Nettles, Brian J.; Doyle, Michael P..
Dirhodium caprolactamate [Rh2(cap)4] is a highly effective catalyst for the oxidative Mannich reaction of tertiary amines with siloxyfurans to provide γ-aminoalkyl butenolides, e.g., I. The reaction proceeds via C-H oxidation of a tertiary amine followed by nucleophilic capture. This green transformation is conducted in protic solvent using inexpensive T-HYDRO (70% t-BuOOH in water).
After consulting a lot of data, we found that this compound(138984-26-6)Safety of Dirhodium(II) tetrakis(caprolactam) can be used in many types of reactions. And in most cases, this compound has more advantages.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI