Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Inorganica Chimica Acta called Selective oxidation of exogenous substrates by a bis-Cu(III) bis-oxide complex: Mechanism and scope, Author is Large, Tao A. G.; Mahadevan, Viswanath; Keown, William; Stack, T. Daniel P., which mentions a compound: 15418-29-8, SMILESS is [Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-], Molecular C8H12BCuF4N4, COA of Formula: C8H12BCuF4N4.
Cu(III)2(μ-O)2 bis-oxides (O) form spontaneously by direct oxygenation of nitrogen-chelated Cu(I) species and constitute a diverse class of versatile 2e-/2H+ oxidants, but while these species have attracted attention as biomimetic models for dinuclear Cu enzymes, reactivity is typically limited to intramol. ligand oxidation, and systems exhibiting synthetically useful reactivity with exogenous substrates are limited. OTMPD (TMPD = N1, N1, N3, N3-tetramethylpropane-1,3-diamine) presents an exception, readily oxidizing a diverse array of exogenous substrates, including primary alcs. and amines selectively over their secondary counterparts in good yields. Mechanistic and DFT analyses suggest substrate oxidation proceeds through initial axial coordination, followed by rate-limiting rotation to position the substrate in the Cu(III) equatorial plane, whereupon rapid deprotonation and oxidation by net hydride transfer occurs. Together, the results suggest the selectivity and broad substrate scope unique to OTMPD are best attributed to the combination of ligand flexibility, limited steric demands, and ligand oxidative stability. In keeping with the absence of rate-limiting C-H scission, OTMPD exhibits a marked insensitivity to the strength of the substrate Cα-H bond, readily oxidizing benzyl alc. and 1-octanol at near identical rates.
After consulting a lot of data, we found that this compound(15418-29-8)COA of Formula: C8H12BCuF4N4 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI