Archives for Chemistry Experiments of 271-95-4

After consulting a lot of data, we found that this compound(271-95-4)Recommanded Product: 1,2-Benzisoxazole can be used in many types of reactions. And in most cases, this compound has more advantages.

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1,2-Benzisoxazole, is researched, Molecular C7H5NO, CAS is 271-95-4, about Gold-Catalyzed Michael-Type Reactions and [4 + 2]-Annulations between Propiolates and 1,2-Benzisoxazoles with Ester-Directed Chemoselectivity, the main research direction is gold catalyzed Michael type reaction annulation propiolate benzisoxazole; ester directed chemoselective reaction Michael type product oxazinone preparation.Recommanded Product: 1,2-Benzisoxazole.

This work reports gold-catalyzed reactions between 1,2-benzisoxazoles and propiolate derivatives with ester-controlled chemoselectivity. For Et propiolates I(R = Ph, 4-BrPh, iPr, etc.; R’ = Et), their gold-catalyzed reactions afforded Michael-type products II (R = Ph, 4-BrPh, iPr, etc.), whereas tert-Bu propiolates I (R = Ph, 4-BrPh, iPr, etc.; R’ = tert-Bu) preferably underwent [4 + 2]-annulations, further yielding 6H-1,3-oxazin-6-one derivatives III (R = Ph, 4-BrPh, iPr, etc.).

After consulting a lot of data, we found that this compound(271-95-4)Recommanded Product: 1,2-Benzisoxazole can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI