Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 138984-26-6, is researched, Molecular C24H40N4O4Rh2, about Study of substrate dependence on the diastereoselectivity of the ruthenium(II) porphyrin catalyzed tandem formation and 1,3-dipolar cycloaddition reactions of carbonyl ylides, the main research direction is stereoselective synthesis dipolar cycloaddition diazo ketone dipolarophile ruthenium porphyrin; oxabicyclooctenone derivative preparation diazo ketone alkene ruthenium porphyrin catalyst; azatricycloundecanone derivative preparation diazo ketone alkene ruthenium porphyrin catalyst; carbonyl ylide formation diazo ketone ruthenium porphyrin.Application of 138984-26-6.
The effect of substrate substitution on reaction selectivity for the ruthenium(II) porphyrin catalyzed tandem carbonyl ylide formation/1,3-dipolar cycloaddition reaction of a variety of alkyl and aryl substituted α-diazo ketones, e.g. I, with π-unsaturated compounds, e.g. II, to give various cycloadducts, e.g. III, was examined The results suggested the diastereoselectivity of the reaction to be highly substrate dependant. Similar yields and cis/trans selectivities have also been achieved for the analogous reactions with rhodium(II,II) dimer as catalyst.
Although many compounds look similar to this compound(138984-26-6)Application of 138984-26-6, numerous studies have shown that this compound(SMILES:C12=O[Rh+2]3(O=C4[N-]5CCCCC4)([N-]6C(CCCCC6)=O7)[N-](CCCCC8)C8=O[Rh+2]357[N-]1CCCCC2), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI