Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60804-74-2, is researched, SMILESS is F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2], Molecular C30H24F12N6P2RuPreprint, arXiv.org, e-Print Archive, Physics called Breaking the selection rules of spin-forbidden molecular absorption in plasmonic nanocavities, Author is Ojambati, Oluwafemi S.; Deacon, William M.; Chikkaraddy, Rohit; Readman, Charlie; Lin, Qianqi; Koczor-Benda, Zsuzsanna; Rosta, Edina; Scherman, Oren A.; Baumberg, Jeremy J., the main research direction is plasmonic nanocavity spin forbidden mol absorption selection rule.Related Products of 60804-74-2.
Controlling absorption and emission of organic mols. is crucial for efficient light-emitting diodes, organic solar cells and single-mol. spectroscopy. Here, a new mol. absorption is activated inside a gold plasmonic nanocavity, and found to break selection rules via spin-orbit coupling. Photoluminescence excitation scans reveal absorption from a normally spin-forbidden singlet to triplet state transition, while drastically enhancing the emission rate by several thousand fold. The exptl. results are supported by d. functional theory, revealing the manipulation of mol. absorption by nearby metallic gold atoms.
Although many compounds look similar to this compound(60804-74-2)Related Products of 60804-74-2, numerous studies have shown that this compound(SMILES:F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI