The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Synthesis and Characterization of a Rare Transition-Metal Oxothiostannate and Investigation of Its Photocatalytic Properties, the main research direction is hydrogen preparation cyclen tin oxosulfide photocatalyst; electrochem redox potential nickel cyclen tin oxosulfide complex; crystal structure nickel cyclen tin oxosulfide complex preparation.HPLC of Formula: 60804-74-2.
The new transition-metal oxothiostannate [Ni(cyclen)(H2O)2]4[Sn10S20O4]·∼13H2O (1) was prepared under hydrothermal conditions using Na4SnS4·14H2O as the precursor in the presence of [Ni(cyclen)(H2O)2](ClO4)2·H2O. Compound 1 comprises the [Sn10S20O4]8- anion constructed by the T3-type supertetrahedron [Sn10S20] and the [Sn10O4] anti-T2 cluster. Channels host the H2O mols., and the sample can be reversibly dehydrated and rehydrated without significantly affecting the crystallinity of the material. 119Sn NMR spectroscopy of an aqueous solution of Na4SnS4·14H2O evidences that between 25 and 120° only [SnS4]4- and [Sn2S6]4- anions are present. In further experiments, hints were found that the formation of tin oxosulfide ions depends on the Ni2+-centered complexes. Compound 1 exhibits promising photocatalytic properties for the visible-light-driven hydrogen evolution reaction, with 18.7 mmol·g-1 H2 being evolved after 3 h.
Compounds in my other articles are similar to this one(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate))HPLC of Formula: 60804-74-2, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI