The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Dirhodium(II) tetrakis(caprolactam)(SMILESS: C12=O[Rh+2]3(O=C4[N-]5CCCCC4)([N-]6C(CCCCC6)=O7)[N-](CCCCC8)C8=O[Rh+2]357[N-]1CCCCC2,cas:138984-26-6) is researched.Computed Properties of C8H12BCuF4N4. The article 《Cycloaddition Chemistry of 2-Vinyl-Substituted Indoles and Related Heteroaromatic Systems》 in relation to this compound, is published in Journal of Organic Chemistry. Let’s take a look at the latest research on this compound (cas:138984-26-6).
The intramol. Diels-Alder cycloaddition reaction (IMDAF) of several N-phenylsulfonylindolyl-substituted furanyl carbamates containing a tethered π-bond on the indole ring were examined as an approach to the iboga alkaloid catharanthine. Only in the case where the tethered π-bond contained two carbomethoxy groups did the [4+2]-cycloaddition occur. Push-pull dipoles generated from the Rh(II)-catalyzed reaction of diazo imides, on the other hand, undergo successful intramol. 1,3-dipolar cycloaddition across both alkenyl and heteroaromatic π-bonds to provide novel pentacyclic compounds (e.g. I) in good yield and in a stereocontrolled fashion. The facility of the cycloaddition was found to be critically dependent on conformational factors in the transition state. Ligand substitution in the rhodium(II) catalyst markedly altered the product ratio between [3+2]-cycloaddition and intramol. C-H insertion. The variation in reactivity reflects the difference in electrophilicity between the various rhodium carbenoid intermediates. Intramol. C-H insertion is enhanced with the more electrophilic carbene generated using Rh(II) perfluorobutyrate.
In some applications, this compound(138984-26-6)COA of Formula: C24H40N4O4Rh2 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI