HPLC of Formula: 271-95-4. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1,2-Benzisoxazole, is researched, Molecular C7H5NO, CAS is 271-95-4, about Physical organic chemistry of benzisoxazoles. I. Mechanism of the base-catalyzed decomposition of benzisoxazoles. Author is Casey, Martha L.; Kemp, D. S.; Paul, Kenneth G.; Cox, Daniel D..
The mechanism of reaction of 5-, 6-, and 7-substituted benzisoxazoles with hydroxide or amines was established as a concerted E-2 elimination yielding o-cyanophenolate anions. With hydroxide in aqueous EtOH, these reactions have a ΔH° in the range of -35 to -39 kcal/mole. The effects of salts and temperature on rates are considered, and the significance of the benzisoxazole system as a new kind of leaving group is discussed.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI