Recommanded Product: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Photocatalytic Fluoro Sulfoximidations of Styrenes. Author is Wang, Chenyang; Tu, Yongliang; Ma, Ding; Bolm, Carsten.
Reactions of difluoroiodotoluene with NH-sulfoximines provide new hypervalent iodine(III) reagents, which photocatalytically transfer a fluoro and a sulfoximidoyl group onto styrenes with high regioselectivity [e.g., stepwise I + II followed by treatment with styrene and photocatalyst under blue LED → III (83%, diastereomer mix)]. The substrate scope is broad with respect to both sulfoximines and olefins. Following an operationally simple protocol, a large library of fluorine-containing N-functionalized sulfoximines can be accessed. Results from mechanistic investigations revealed the importance of radical intermediates.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI