Nayal, Onkar S.; Hong, Junting; Yang, Yang; Mo, Fanyang published the article 《Cu-Catalysed carboxylation of aryl boronic acids with CO2》. Keywords: arylboronic acid carbon dioxide copper NHC catalyst caboxylation; aryl carboxylic acid preparation.They researched the compound: Quinolin-6-ylboronic acid( cas:376581-24-7 ).Recommanded Product: 376581-24-7. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:376581-24-7) here.
A copper/N-heterocyclic carbene (NHC) catalyzed carboxylation of arylboronic acids under one atm. pressure of CO2 was developed. A wide range of arylboronic acids was transformed into benzoic acid derivatives in moderate to high yields. The carboxylation method showed excellent functional group compatibility and sensitive functional groups such as carbonyls, esters and nitriles were tolerated. Mechanistic studies revealed the vital role of the base in promoting the transmetalation step for this copper-catalyzed carboxylation.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI