Huang, Ting-Hong; Wu, Tian-Cheng; Zhao, Fang-Zheng; Zheng, Dan; Luo, Cheng; Liang, Guang-Ming; Zhao, Bin published an article about the compound: Copper(I) tetra(acetonitrile) tetrafluoroborate( cas:15418-29-8,SMILESS:[Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-] ).Recommanded Product: Copper(I) tetra(acetonitrile) tetrafluoroborate. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:15418-29-8) through the article.
A mononuclear Cu(I) complex, [Cu(dppb)(2,2′-biquinoline)]BF4 (1) (dppb = 1, 2-bis(di-Phphosphino)benzene), was synthesized and characterized at 100 K, 150 K, 200 K, 250 K and 298 K. The structural anal. reveals that the rise of temperature from 100 K to 298 K leads to the increasement of mol. size, such as the unit-cell parameters and volume, and the change of bond lengths, bond angles, C-H…π and π…π interactions. DFT calculations indicate that the HOMO → LUMO energy gap and Mulliken at. charges are changed by the increase of temperature from 100 K to 298 K, and the component of the HOMOs and LUMOs are barely changed at 100-298 K, which is in accordance with the variation of DOS and PDOS at different temperatures Meanwhile, the surprising broad blue-yellow excitation bands are observed at 100-298 K and the maximum emission is increasing with the blue shift from 735 nm at 100 K to 685 nm at 298 K. Furthermore, the emission decay time of complex 1 reaches 3μs at 298 K. In addition, copper(I) complex 1 was used to fabricate the monochromatic LED, which emits a red light.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI