Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Polymer immobilization effect on excited state of emitting copper complex: Synthesis, characterization and performance improvement.HPLC of Formula: 15418-29-8.
In this effort, the correlation between polymer immobilization effect and excited state of emitting Cu complex was discussed. An electron-pulling diamine ligand having an oxadiazole ring and a F atom was synthesized. Its corresponding Cu(I) complex was synthesized with a phosphorus ligand (PPh3) having obvious steric hindrance as auxiliary ligand. Its geometric structure, electronic transition and photophys. parameters were discussed. A distorted tetrahedral coordination field was adopted by this Cu(I) complex. Its onset electronic transition was confirmed as a charge transfer 1 and suffered from structural relaxation badly. Using electrospinning method, this Cu(I) complex was dispersed and immobilized into a polymer host so that structural relaxation of its excited state could be limited. A systematical comparison between various states of this complex, in solution, in solid state and in fibrous samples, was performed. It was finally confirmed that this polymer matrix served as a promising supporting host, offering a rigid and protective microenvironment for dopant mols. which effectively limited their MLCT structural relaxation and improved their photostability.
This literature about this compound(15418-29-8)HPLC of Formula: 15418-29-8has given us a lot of inspiration, and I hope that the research on this compound(Copper(I) tetra(acetonitrile) tetrafluoroborate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI