So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Verma, Sanjeev K.; Ghorpade, Ramarao; Kaushik, M. P. researched the compound: 2-Chloro-6-nitrobenzo[d]thiazole( cas:2407-11-6 ).Safety of 2-Chloro-6-nitrobenzo[d]thiazole.They published the article 《Arylation of Amines and Monoarylation of Symmetrical Diamines in the Presence of Brine Solution with Diheteroaryl Halides》 about this compound( cas:2407-11-6 ) in Synthetic Communications. Keywords: arylamine preparation; monoaryldiamine preparation; amine aryl halide arylation phase transfer catalyst. We’ll tell you more about this compound (cas:2407-11-6).
A simple, scalable, ligand-free, and metal-free protocol for arylation of amines and monoarylation of sym. diamines with diheteroaryl halides in the presence of brine solution has been developed. The protocol has broad structural applicability for chemoselective monoarylation of a wide variety of sym., cyclic, and acyclic aliphatic diamines. The protocol is also applicable for selective arylation of aliphatic amine in the presence of aromatic amine.
In addition to the literature in the link below, there is a lot of literature about this compound(2-Chloro-6-nitrobenzo[d]thiazole)Safety of 2-Chloro-6-nitrobenzo[d]thiazole, illustrating the importance and wide applicability of this compound(2407-11-6).
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI