Related Products of 60804-74-2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Photocatalytic Synthesis of Difluoroacetoxy-containing Sulfoximines. Author is Wang, Chenyang; Tu, Yongliang; Ma, Ding; Ait Tarint, Chaimae; Bolm, Carsten.
[Bis(difluoroacetoxy)iodo]benzene and NH-sulfoximines reacted to give new hypervalent iodine(III) reagents, which under photocatalysis transferred difluoroacetoxy and sulfoximidoyl groups to styrenes with high regioselectivity. The results of mechanistic investigations suggested the intermediacy of radicals and revealed the importance of the difluoroacetoxy group on the iodine reagent.
In addition to the literature in the link below, there is a lot of literature about this compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate))Related Products of 60804-74-2, illustrating the importance and wide applicability of this compound(60804-74-2).
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI