The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1-Boc-4-Bromoindole, is researched, Molecular C13H14BrNO2, CAS is 676448-17-2, about Palladium-catalyzed cross-couplings of lithium arylzincates with aromatic halides: synthesis of analogues of isomeridianin G and evaluation as GSK-3β inhibitors, the main research direction is isomeridianin preparation GSK inhibition; Palladium catalyzed cross coupling lithium arylzincate aromatic halide.Name: 1-Boc-4-Bromoindole.
Several analogs of isomeridianin G have been synthesized using palladium-catalyzed cross-coupling reactions of lithium triorganozincates as a key step. The latter have been prepared by deprotonative lithiation followed by transmetalation using ZnCl2·TMEDA (0.33 equiv). Finally, the isomeridianin G analogs have been tested for their inhibition of GSK-3β and their IC50 values have been greatly improved over isomeridianin G.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI