Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, Non-U.S. Gov’t, Nature Communications called Modular synthesis of α-fluorinated arylmethanes via desulfonylative cross-coupling, Author is Nambo, Masakazu; Yim, Jacky C.-H.; Freitas, Luiza B. O.; Tahara, Yasuyo; Ariki, Zachary T.; Maekawa, Yuuki; Yokogawa, Daisuke; Crudden, Cathleen M., which mentions a compound: 376581-24-7, SMILESS is OB(C1=CC=C2N=CC=CC2=C1)O, Molecular C9H8BNO2, Application In Synthesis of Quinolin-6-ylboronic acid.
Herein, Pd-catalyzed Suzuki-Miyaura cross-coupling of α-fluorinated benzylic triflones with arylboronic acids affording structurally diverse α-fluorinated diarylmethanes Ar1C(X)(F)Ar2 [Ar1 = 4-t-BuC6H4, 4-O2NC6H4, 4-CO2MeC6H4, etc.; Ar2 = Ph, 2-MeC6H4, 1-naphthyl, etc.] was reported. The ease of synthesis of fluorinated triflones as the key starting materials enabled powerful late-stage transformations of known biol. active compounds into fluorinated analogs.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI