Name: 2-Chloro-6-nitrobenzo[d]thiazole. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 2-Chloro-6-nitrobenzo[d]thiazole, is researched, Molecular C7H3ClN2O2S, CAS is 2407-11-6, about NMR-based assignment of isoleucine vs. allo-isoleucine stereochemistry. Author is Anderson, Zoe J.; Hobson, Christian; Needley, Rebecca; Song, Lijiang; Perryman, Michael S.; Kerby, Paul; Fox, David J..
A simple 1H and 13C NMR spectrometric anal. is demonstrated that permits differentiation of isoleucine and allo-isoleucine residues by inspection of the chem. shift and coupling constants of the signals associated with the proton and carbon at the α-stereocenter. This is applied to the estimation of epimerization during metal-free N-arylation and peptide coupling reactions.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI