Related Products of 376581-24-7. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Quinolin-6-ylboronic acid, is researched, Molecular C9H8BNO2, CAS is 376581-24-7, about Catalytic Asymmetric Radical Diamination of Alkenes. Author is Wang, Fu-Li; Dong, Xiao-Yang; Lin, Jin-Shun; Zeng, Yang; Jiao, Guan-Yuan; Gu, Qiang-Shuai; Guo, Xian-Qi; Ma, Can-Liang; Liu, Xin-Yuan.
The use of O-acylhydroxylamines as dialkylaminyl radical precursors to trigger asym. diamination of alkenes under Cu(I)/chiral phosphoric acid dual catalysis is reported. This reaction allows for direct alkylamine incorporation and features high enantioselectivity, a broad substrate scope, wide functional-group tolerance and mild reaction conditions, providing convenient and practical access to a wide range of highly enantio-enriched β-alkylamine-containing pyrrolidines. Asym. azidoamination of alkenes by using azidoiodinane as an azidyl radical precursor, offering a complementary method for preparing diverse chiral β-amino pyrrolidines, was also achieved. The application of the resultant α-tertiary pyrrolidine-derived diamine was showcased to significantly promote the enantioselectivity of an asym. Michael reaction.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI