Name: 2-Bromopropanenitrile. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-Bromopropanenitrile, is researched, Molecular C3H4BrN, CAS is 19481-82-4, about An atom transfer radical polymerization system: catalyzed by an iron catalyst in PEG-400. Author is Ding, Mingqiang; Jiang, Xiaowu; Peng, Jinying; Zhang, Lifen; Cheng, Zhenping; Zhu, Xiulin.
A green and highly efficient AGET ATRP (activators generated by electron transfer for atom transfer radical polymerization) system was constructed in the absence of any addnl. ligands, using FeCl3·6H2O as a catalyst, and Me methacrylate as a model monomer in polyethylene glycol 400 (PEG-400). The effects of various factors, such as the type of ATRP initiator, the mol. weight of PEG and the reducing agent type, polymerization temperature as well as solvent, on the polymerization were investigated. Polymerization kinetics demonstrated that the polymerization was a controlled/””living”” process with mol. weight increasing linearly with conversion while maintaining a low mol. weight distribution. The living feature was further confirmed by chain extension experiments
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