Name: Copper(I) tetra(acetonitrile) tetrafluoroborate. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Divergent Chemistry Paths for 3D and 1D Metallo-Covalent Organic Frameworks (COFs). Author is Xu, Hai-Sen; Luo, Yi; See, Pei Zhen; Li, Xing; Chen, Zhongxin; Zhou, Yi; Zhao, Xiaoxu; Leng, Kai; Park, In-Hyeok; Li, Runlai; Liu, Cuibo; Chen, Fangzheng; Xi, Shibo; Sun, Junliang; Loh, Kian Ping.
The marriage of dynamic covalent chem. (DCC) and coordination chem. is a powerful tool for assembling complex architectures from simple building units. Recently, the synthesis of woven covalent organic frameworks (COFs) with topol. fascinating structures has been achieved using this approach. However, the scope is highly limited and there is a need to discover new pathways that can assemble covalently linked organic threads into crystalline frameworks. Herein, authors have identified branching pathways leading to the assembly of three-dimensional (3D) woven COFs or one-dimensional (1D) metallo-COFs (mCOFs), where the mechanism is underpinned by the absence or presence of ligand exchange.
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