Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 15418-29-8, is researched, SMILESS is [Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-], Molecular C8H12BCuF4N4Journal, Article, Journal of the American Chemical Society called [Cu81(PhS)46(tBuNH2)10(H)32]3+ Reveals the Coexistence of Large Planar Cores and Hemispherical Shells in High-Nuclearity Copper Nanoclusters, Author is Huang, Ren-Wu; Yin, Jun; Dong, Chunwei; Ghosh, Atanu; Alhilaly, Mohammad J.; Dong, Xinglong; Hedhili, Mohamed Nejib; Abou-Hamad, Edy; Alamer, Badriah; Nematulloev, Saidkhodzha; Han, Yu; Mohammed, Omar F.; Bakr, Osman M., the main research direction is copper thiophenolate butylamine nanocluster preparation crystal structure hydrogen evolution.Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate.
Cu-based nanomaterials have attracted tremendous interest due to their unique properties in the fields of photoluminescence and catalysis. As a result, studies on the correlation between their mol. structure and their properties are of great importance. Cu nanoclusters are a new class of nanomaterials that can provide an at.-level view of the crystal structure of Cu nanoparticles. Herein, a high-nuclearity Cu nanocluster with 81 Cu atoms, formulated as [Cu81(PhS)46(tBuNH2)10(H)32]3+ (Cu81), was successfully synthesized and fully studied by x-ray crystallog., XPS, H evolution experiments, electrospray ionization mass spectrometry, NMR spectroscopy, and d. functional theory calculations Cu81 exhibits extraordinary structural characteristics, including (i) three types of novel epitaxial surface-protecting motifs; (ii) an unusual planar Cu17 core; (iii) a hemispherical shell, comprised of a curved surface layer and a planar surface layer; and (iv) two distinct, self-organized arrangements of protective ligands on the curved and planar surfaces. The present study sheds light on structurally unexplored Cu nanomaterials and paves the way for the synthesis of high-nuclearity Cu nanoclusters.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI