Computed Properties of C24H40N4O4Rh2. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about Facile generation of aziridines from the reaction of α-diazoamides with tethered oximino-ethers. Author is McMills, Mark C.; Wright, Dennis L.; Zubkowski, Jeffrey D.; Valente, Edward J..
Preparation of the central diazabicyclo[3.2.1]octane (I) core of quinocarcin via azomethine ylide intermediates generated from metal catalyzed cycloaddition of an electron deficient olefin with oximino-ether (II) containing a tethered α-diazoamide moiety was attempted. Cyclization of II with Me acrylate in the presence of several metal catalysts, e.g. Rh2(OAc)4 and Cu(acac)2, resulted in the formation of aziridine III with, at most, only trace amounts of the desired target compound I being formed when Cu(acac)2 and Cu(hfaca)2 were used as the catalysts.
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