Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60804-74-2, is researched, SMILESS is F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2], Molecular C30H24F12N6P2RuJournal, Youji Huaxue called Visible-light-induced α-C (sp3)-H amination reactions of tertiary amines, Author is Zhao, Yating; Zeng, Junjie; Xia, Wujiong, the main research direction is visible light alpha amination tertiary amine preparation.Quality Control of Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate).
Herein, the visible-light-induced α-C (sp3)-H amination reactions of tertiary amines were reported. By using readily available 1,3-dioxoisoindolin-2-yl benzoate as precursor of N-radical and blue LEDs as green and sustainable energy source, the α-C (sp3)-H bonds of various N,N-dimethylaniline derivatives were aminated directly. Based on radical trapping experiment and documented literature, a mechanism involving radicals coupling was proposed. This method features in mild reaction conditions and good functional group tolerance, which provides a simple and practical protocol to the modification of tertiary amines.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI