Related Products of 138984-26-6. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about Unusual formation of 7-vinylcycloheptatriene derivatives in the catalytic cyclopropanation of cyclooctatetraene with diazocarbonyl compounds in the presence of rhodium catalysts.
The reaction of cyclooctatetraene with Me diazoacetate or diazoacetone in the presence of Rh binuclear complexes gives, besides 9-substituted bicyclo[6.1.0]nona-2,4,6-trienes (mixture of anti- and syn-isomers, total yields 60-75%), isomeric β-(cyclohepta-2,4,6-trien-l-yl)acrylates or 4-(cyclohepta-2,4,6-trien-l-yl)but-3-en-2-one in 20-34% yields. In the case of Me diazoacetate, a mixture of E- and Z-isomers in a ratio of ∼3.5: 1 was obtained, while diazoacetone gave only E-isomer.
I hope my short article helps more people learn about this compound(Dirhodium(II) tetrakis(caprolactam))Related Products of 138984-26-6. Apart from the compound(138984-26-6), you can read my other articles to know other related compounds.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI