Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, N.I.H., Extramural, Research Support, Non-U.S. Gov’t, Angewandte Chemie, International Edition called Synthesis of (±)-Tetrapetalone A-Me Aglycon, Author is Carlsen, Peter N.; Mann, Tyler J.; Hoveyda, Amir H.; Frontier, Alison J., which mentions a compound: 138984-26-6, SMILESS is C12=O[Rh+2]3(O=C4[N-]5CCCCC4)([N-]6C(CCCCC6)=O7)[N-](CCCCC8)C8=O[Rh+2]357[N-]1CCCCC2, Molecular C24H40N4O4Rh2, Product Details of 138984-26-6.
The first synthesis of (±)-tetrapetalone A-Me aglycon (I) is described. Key bond-forming reactions include Nazarov cyclization, a ring-closing metathesis promoted with complete diastereoselectivity by a chiral molybdenum-based complex, tandem conjugate reduction/intramol. aldol cyclization, and oxidative dearomatization.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
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