Reference of 2-Chloro-6-nitrobenzo[d]thiazole. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2-Chloro-6-nitrobenzo[d]thiazole, is researched, Molecular C7H3ClN2O2S, CAS is 2407-11-6, about A DBU-diheteroaryl halide adduct as the fastest current N-diheteroarylating agent. Author is Verma, Sanjeev K.; Acharya, B. N.; Ghorpade, Ramarao; Pratap, Ajay; Kaushik, M. P..
An unexpected diazabicyclo[5.4.0]undec-7-ene (DBU) catalyzed rate enhancement of N-arylation of amines with diheteroaryl halides was reported. DBU was found to activate the Ar-Cl bond of a diheteroaryl halide, forming a green colored adduct under neat conditions. The activated green colored adduct was used for the arylation of amines under neat conditions and was found to be the fastest diheteroarylating agent reported to date.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
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