The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Copper-Catalyzed Late-Stage Benzylic C(sp3)-H Trifluoromethylation, the main research direction is benzylic trifluoromethylation copper catalyst selective.Safety of Copper(I) tetra(acetonitrile) tetrafluoroborate.
The copper-catalyzed benzylic C(sp3)-H trifluoromethylation was described. With Cu(I) or Cu(II) as the catalyst, (bpy)Zn(CF3)2 (bpy = 2,2′-bipyridine) as the CF3 source, and NFSI (or Selectfluor) as the oxidant, site-selective benzylic C(sp3)-H trifluoromethylation was successfully implemented in high efficiency under mild conditions. The protocol not only exhibits broad substrate scope and wide functional-group compatibility but also allows efficient late-stage C(sp3)-H trifluoromethylation of natural products e.g., I or drug derivatives e.g., II.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI