The influence of catalyst in reaction 15418-29-8

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Pei, Xiao-Li; Guan, Zong-Jie; Nan, Zi-Ang; Wang, Quan-Ming published the article 《Heterometallic Coinage Metal Acetylenediide Clusters Showing Tailored Thermochromic Luminescence》. Keywords: gold silver acetelyenediide phenylbispyridylphosphine complex preparation frontier mol orbital; crystal structure gold silver acetelyenediide phenylbispyridylphosphine complex; acetylenediide template; bi-/tri-heterometallic clusters; coinage metals; thermochromic luminescence.They researched the compound: Copper(I) tetra(acetonitrile) tetrafluoroborate( cas:15418-29-8 ).Recommanded Product: Copper(I) tetra(acetonitrile) tetrafluoroborate. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:15418-29-8) here.

Acetelyenediide (C22-) species have been encapsulated in bimetallic and trimetallic clusters: [(AuL)6Ag7(CC)3](BF4)7 (2) and [(AuL)6AgCu6(CC)3](BF4)7 (3), L = phenylbis(2-pyridyl)phosphine (PPhpy2). Single-crystal X-ray diffraction anal. revealed that they are isostructural and six silver atoms in 2 are replaced with copper in 3. Both clusters have a trefoil skeleton, which can be viewed as three trigonal bipyramidal (LAu-CC-AuL)M2Ag (M = Ag/Cu) motifs sharing a common silver atom. TDDFT calculations showed Cu-doping significantly increases the energy level of (C2-Cu)-involved occupied orbital, thus inducing interesting transition coupling of dual-emission at low temperature This work not only provides a strategy for constructing heterometallic clusters, but also shows the prospect for pursuing novel thermochromic luminescent materials by incorporating multi-congeneric metal components.

From this literature《Heterometallic Coinage Metal Acetylenediide Clusters Showing Tailored Thermochromic Luminescence》,we know some information about this compound(15418-29-8)Recommanded Product: Copper(I) tetra(acetonitrile) tetrafluoroborate, but this is not all information, there are many literatures related to this compound(15418-29-8).

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI