The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)( cas:60804-74-2 ) is researched.Recommanded Product: 60804-74-2.Dai, Lei; Ye, Song published the article 《Photo/N-Heterocyclic Carbene Co-catalyzed Ring Opening and γ-Alkylation of Cyclopropane Enal》 about this compound( cas:60804-74-2 ) in Organic Letters. Keywords: photochem heterocyclic carbene catalyst ring opening alkylation cyclopropane enal; alkylated unsaturated ester preparation. Let’s learn more about this compound (cas:60804-74-2).
An unprecedented photo/NHC-co-catalyzed ring-opening C-C bond cleavage of cyclopropane enal and the following γ-alkylation with a halogenated compound via radicals were established, affording the corresponding γ-alkylated α,β-unsaturated esters in moderate to good yields.
There is still a lot of research devoted to this compound(SMILES：F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2])Recommanded Product: 60804-74-2, and with the development of science, more effects of this compound(60804-74-2) can be discovered.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI