The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)(SMILESS: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2],cas:60804-74-2) is researched.Formula: C6H6N2O. The article 《Phosphoramidates as Transient Precursors of Nitrogen-Centered Radical Under Visible-Light Irradiation: Application to the Synthesis of Phthalazine Derivatives》 in relation to this compound, is published in Advanced Synthesis & Catalysis. Let’s take a look at the latest research on this compound (cas:60804-74-2).
Phosphoramidates are for the first time presented as efficient N-Centered Radical (NCR) precursors under visible-light irradiation More precisely among this class of phosphorus-derived compounds, the radical reactivity of phosphonohydrazones, e.g I, was studied, under mild reaction conditions, which allowed the synthesis of a wide and diversified library of the scarcely reported phthalazine scaffold. Mechanistic investigations confirmed the formation of a NCR from these brand-new phosphonohydrazones (derivatived from phosphoramidates), which were further engaged in an intramol. 6-exo-dig cyclization to provide phthalazines. Compared to other pre-activated moieties, the phosphoramidate group is self-immolative, thus enhancing its attractiveness for the C-N bond formation.
In some applications, this compound(60804-74-2)Electric Literature of C30H24F12N6P2Ru is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI