Nandi, Jyoti; Vaughan, Matthew Z.; Sandoval, Arturo Leon; Paolillo, Joshua M.; Leadbeater, Nicholas E. published the article 《Oxidative Amidation of Amines in Tandem with Transamidation: A Route to Amides Using Visible-Light Energy》. Keywords: amide preparation blue LED photocatalyzed oxidative amidation amine transamidation.They researched the compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)( cas:60804-74-2 ).Quality Control of Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:60804-74-2) here.
A methodol. is reported for preparing amides using amines as an acyl source. The protocol involves the visible-light-promoted oxidative amidation of amines with pyrazole to synthesize N-acyl pyrazoles followed by transamidation. By combining photoredox catalysis with oxoammonium cations in the presence of sodium persulfate as a terminal oxidant, the N-acyl pyrazoles could be prepared efficiently and effectively using blue LEDs. The transamidation step was performed without the need to purify the N-acyl pyrazole intermediate, and a range of amides were generated in good to excellent yields.
In some applications, this compound(60804-74-2)Quality Control of Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate) is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI