In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called N-H bond formation in a manganese(V) nitride yields ammonia by light-driven proton-coupled electron transfer, published in 2019-03-27, which mentions a compound: 60804-74-2, Name is Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), Molecular C30H24F12N6P2Ru, Electric Literature of C30H24F12N6P2Ru.
A method for the reduction of a manganese nitride to ammonia is reported, where light-driven proton-coupled electron transfer enables the formation of weak N-H bonds. Photoreduction of (saltBu)MnVN to ammonia and a Mn(II) complex has been accomplished using 9,10-dihydroacridine and a combination of an appropriately matched photoredox catalyst and weak Bronsted acid. Acid-reductant pairs with effective bond dissociation free energies between 35 and 46 kcal/mol exhibited high efficiencies. This light-driven method may provide a blueprint for new approaches to catalytic homogeneous ammonia synthesis under ambient conditions.
Here is just a brief introduction to this compound(60804-74-2)Electric Literature of C30H24F12N6P2Ru, more information about the compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate)) is in the article, you can click the link below.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI